Ethanol



GENERAL

Ethanol is a clear, colourless liquid with a characteristic pleasant odour and burning taste. It is highly flammable. Ethanol is used to dissolve other chemical substances and mixes readily with water and many organic liquids. Ethanol is considered a volatile organic compound by the National Pollutant Inventory.

Ethanol, also called alcohol, ethyl alcohol and grain alcohol, is a clear, colorless liquid and the principle ingredient in alcoholic beverages like beer, wine or brandy. Because it can readily dissolve in water and other organic compounds, ethanol also is an ingredient in a range of products, from personal care and beauty products to paints and varnishes to fuel.



Transportation of Ethanol via Highway

Since both gasoline and ethanol-blended fuels have very similar physical and chemical characteristics, they will be transported in the same general types of containers and tanks. The most prevalent style of transport of the blended fuels that emergency responders will encounter will be by MC-306 and Department of Transportation (DOT)-406 style road tankers with 3/8-inch aluminum tanks. These tankers are non-pressurized dual-axle, come in a variety of sizes and configurations, and have a capacity up to 6,000-9,500 gallons depending on where responders are located. The tanker itself may also have up to seven compartments.

Cargo tank trucks are placarded and marked similar to other products. Other characteristics of the cargo tank are pressure and vacuum relief devices. They are typically bottom loaded and unloaded and equipped with a vapor recovery system. Safety devices on these tank trucks consist of emergency shutoffs, breakaway valves for sheer protection, pressure relief devices as well as overfill and collision protection.


Physical properties

Ethanol is a monohydric primary alcohol. It melts at -117.3°C and boils at 78.5°C. It is miscible (i.e., mixes without separation) with water in all proportions and is separated from water only with difficulty; ethanol that is completely free of water is called absolute ethanol. Ethanol forms a constant-boiling mixture, or azeotrope, with water that contains 95% ethanol and 5% water and that boils at 78.15°C; since the boiling point of this binary azeotrope is below that of pure ethanol, absolute ethanol cannot be obtained by simple distillation. However, if benzene is added to 95% ethanol, a ternary azeotrope of benzene, ethanol, and water, with boiling point 64.9°C, can form; since the proportion of water to ethanol in this azeotrope is greater than that in 95% ethanol, the water can be removed from 95% ethanol by adding benzene and distilling off this azeotrope. Because small amounts of benzene may remain, absolute ethanol prepared by this process is poisonous. Ethanol burns in air with a blue flame, forming carbon dioxide and water. It reacts with active metals to form the metal ethoxide and hydrogen, e.g., with sodium it forms sodium ethoxide. It reacts with certain acids to form esters, e.g., with acetic acid it forms ethyl acetate. It can be oxidized to form acetic acid and acetaldehyde. It can be dehydrated to form diethyl ether or, at higher temperatures, ethylene.



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